1,4-Dibenzyl-1,4-diazoniabicyclo[2.2.2]-octane chlorochromate (DBDABOCC): A mild and selective reagent for efficient oxidation of organic compounds under non-aqueous conditions

Authors
Mohammadpoor-Baltork, I Hajipour, AR Ghahramankhani, A
Citation
I. Mohammadpoor-baltork et al., 1,4-Dibenzyl-1,4-diazoniabicyclo[2.2.2]-octane chlorochromate (DBDABOCC): A mild and selective reagent for efficient oxidation of organic compounds under non-aqueous conditions, I J CHEM B, 39(11), 2000, pp. 863-866
Citations number
18
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY
ISSN journal
03764699 → ACNP
Volume
39
Issue
11
Year of publication
2000
Pages
863 - 866
Database
ISI
SICI code
0376-4699(200011)39:11<863:1C(A>2.0.ZU;2-N
Abstract
The preparation of 1,4-dibenzyl-1,4-diazoniabicyclo[2.2.2]octane chlorochro mate 1 is described. With this reagent benzylic and allylic alcohols are se lectively oxidized to their corresponding carbonyl compounds in excellent y ields. Grimes, thiols and aromatic amines are also converted to their corre sponding carbonyl compounds, disulfides and azo compounds efficiently.