Syntheses, structures and magnetic properties of 1-D coordination polymerscontaining both dicyanamide and 2-pyrrolidone

Authors
Sun, BW Gao, S Ma, BQ Wang, ZM
Citation
Bw. Sun et al., Syntheses, structures and magnetic properties of 1-D coordination polymerscontaining both dicyanamide and 2-pyrrolidone, INORG CH C, 4(2), 2001, pp. 72-75
Citations number
14
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
4
Issue
2
Year of publication
2001
Pages
72 - 75
Database
ISI
SICI code
1387-7003(200102)4:2<72:SSAMPO>2.0.ZU;2-V
Abstract
Structures of two 1-D coordination polymers, [M-II(pyr)(2)(N(CN)(2))(2)] (M = Mn (1), Co (2), pyr=2-pyrrolidone), have been determined. They are isomo rphous and belong to monoclinic space group, Cm with Z = 2. The magnetic pr operties of two compounds (2-300 K) show thr existence of weak antiferromag netic exchange interaction between paramagnetic centers along chains. (C) 2 001 Elsevier Science B.V. All rights reserved.