Heteropolymetallic assemblies constructed from homometallic coordination polymers and paramagnetic metal-containing anions. Synthesis, crystal structure and magnetic properties of [Mn(4,4 '-bipyridine-N,N '-dioxide) (H2O)(4)][Cr(bipy)(C2O4)(2)](2)center dot 8H(2)O

Authors
Bruda, S Andruh, M Roesky, HW Journaux, Y Noltemeyer, M Riviere, E
Citation
S. Bruda et al., Heteropolymetallic assemblies constructed from homometallic coordination polymers and paramagnetic metal-containing anions. Synthesis, crystal structure and magnetic properties of [Mn(4,4 '-bipyridine-N,N '-dioxide) (H2O)(4)][Cr(bipy)(C2O4)(2)](2)center dot 8H(2)O, INORG CH C, 4(2), 2001, pp. 111-114
Citations number
16
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
4
Issue
2
Year of publication
2001
Pages
111 - 114
Database
ISI
SICI code
1387-7003(200102)4:2<111:HACFHC>2.0.ZU;2-M
Abstract
The reaction of the Mn2+ (aq) and [Cr(bipy)(C2O4)(2)](-) (aq) ions with 4,4 '-bipyridine-N,N'-dioxide leads to a heteropolymetallic system, [Mn(4,4'-bi pyridine-N,N'-dioxide) (H2O)(4)][Cr(bipy)(C2O4)(2)](2) . 8H(2)O (1) The cry stal structure of 1 consists of one-dimensional chains, (1)(infinity)[Mn(4, 4'-bipyridine-N,N'-dioxide) (H2O)(4)](n)(2n+), with Mn(II) ions bridged by 4,4'-bipyridine-N N'-dioxide ligands. The infinite homometallic chains are interconnected through hydrogen bonds with the water molecules and the [Cr( bipy)(C2O4)(2)](-) anions. The cryomagnetic measurements of compound 1 reve al weak anti-ferromagnetic interactions between the manganese(II) ions with in the chain (J= -1.2 cm(-1)). (C) 2001 Published by Elsevier Science B.V. All rights reserved.