We have performed non-degenerate four-wave mixing on free-standing por
ous Si samples, Within the framework of an idealized inhomogeneously b
roadened two-level system, values of 20 fs for the dephasing time are
obtained for different porosities. Fast energy relaxation times are fo
und in the range 1.5-3.5 ps for 64-73% porosities, respectively. They
are attributed to carrier thermalization within the band tails, origin
ating from porous silicon nanocrystallites and their surface states. (
C) 1997 Elsevier Science S.A.