Tethering strategies in alkynylamino carbene complexes

Authors
Moreto, JM Ricart, S
Citation
Jm. Moreto et S. Ricart, Tethering strategies in alkynylamino carbene complexes, J ORGMET CH, 617(1), 2001, pp. 334-338
Citations number
21
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
617
Issue
1
Year of publication
2001
Pages
334 - 338
Database
ISI
SICI code
0022-328X(20010115)617:1<334:TSIACC>2.0.ZU;2-I
Abstract
During the synthesis of complex cyclic macromolecular structures, the react ion of different mono- di- and triamino alkynyl metal carbene systems with primary and secondary amines was studied. The results showed the low stabil ity of the metal carbene complexes obtained from the conjugate addition of primary amines in contrast to the fairly good stability of the correspondin g complexes obtained from the addition of secondary amines. (C) 2001 Elsevi er Science B.V. All rights reserved.