FORMATION OF A CARBON-DIOXIDE COMPLEX OF RHENIUM VIA FORMAL OXIDATIONOF A CARBON-MONOXIDE LIGAND

Authors
WANG TF HWU CC TSAI CW LIN KJ
Citation
Tf. Wang et al., FORMATION OF A CARBON-DIOXIDE COMPLEX OF RHENIUM VIA FORMAL OXIDATIONOF A CARBON-MONOXIDE LIGAND, Organometallics, 16(14), 1997, pp. 3089-3090
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
14
Year of publication
1997
Pages
3089 - 3090
Database
ISI
SICI code
0276-7333(1997)16:14<3089:FOACCO>2.0.ZU;2-R
Abstract
The reaction of aminorhenium carbonyl complex 1 with MCPBA provides th e aminorhenium eta(2)-CO2 complex 2 in 97% yield. Bromination of 1 fol lowed by treatment of the resultant bromide with NaOH also provides 2 in 90% yield.