SYNTHESIS, STRUCTURES, AND REACTIVITIES OF RHODIUM AND RUTHENIUM COMPLEXES WITH A NOVEL CHIRAL CYCLOPENTADIENYL-FERROCENYLDIPHENYLPHOSPHINEBIDENTATE LIGAND

Authors
NISHIBAYASHI Y TAKEI I HIDAI M
Citation
Y. Nishibayashi et al., SYNTHESIS, STRUCTURES, AND REACTIVITIES OF RHODIUM AND RUTHENIUM COMPLEXES WITH A NOVEL CHIRAL CYCLOPENTADIENYL-FERROCENYLDIPHENYLPHOSPHINEBIDENTATE LIGAND, Organometallics, 16(14), 1997, pp. 3091-3093
Citations number
39
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
14
Year of publication
1997
Pages
3091 - 3093
Database
ISI
SICI code
0276-7333(1997)16:14<3091:SSAROR>2.0.ZU;2-F
Abstract
Novel rhodium(I) and ruthenium(II) complexes with the chiral cyclopent adienyl-phosphine bidentate ligand PPFCp have been prepared and charac terized crystallographically. The cationic ruthenium-vinylidene comple x [Ru(C=CHPh)(PPh3)(PPFCp)]PF6, obtained from [RuCl(PPh3)(PPFCp)] and phenylacetylene, reacts with 1-buten-3-ol to afford 3-methyl-1-phenyl- 4-penten-2-one in moderate yield with moderate enantioselectivity.