SYNTHESIS OF [TI(ETA(6)-1,3,5-(C6H3PR3)-PR-I)(2)][BAR4] (AR=C6H5, P-C6H4F, 3,5-C6H3(CF3)(2)), THE FIRST TITANIUM(I) DERIVATIVES

Authors
CALDERAZZO F FERRI I PAMPALONI G ENGLERT U GREEN MLH
Citation
F. Calderazzo et al., SYNTHESIS OF [TI(ETA(6)-1,3,5-(C6H3PR3)-PR-I)(2)][BAR4] (AR=C6H5, P-C6H4F, 3,5-C6H3(CF3)(2)), THE FIRST TITANIUM(I) DERIVATIVES, Organometallics, 16(14), 1997, pp. 3100-3101
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
14
Year of publication
1997
Pages
3100 - 3101
Database
ISI
SICI code
0276-7333(1997)16:14<3100:SO[(P>2.0.ZU;2-5
Abstract
The oxidation of Ti(eta(6)-1,3,5-(C6H3Pr3)-Pr-i)(2) with FeCp2[BAr4], Ar = C6H5, p-C6H4F, 3,5-C6H3(CF3)(2), affords good yields of the param agnetic derivatives of titanium(I), [Ti(eta(6)-1,3,5-(C6H3Pr3)-Pr-i)(2 )][BAr4]; these compounds have been characterized by conventional meth ods, including single-crystal X-ray diffractometry of i(eta(6)-1,3,5-( C6H3Pr3)-Pr-i)(2)][B(p-C6H4F)(4)].