Iodination of organic substrates with halide salts and H2O2 using an organotelluride catalyst

Authors
Higgs, DE Nelen, MI Detty, MR
Citation
De. Higgs et al., Iodination of organic substrates with halide salts and H2O2 using an organotelluride catalyst, ORG LETT, 3(3), 2001, pp. 349-352
Citations number
27
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
3
Issue
3
Year of publication
2001
Pages
349 - 352
Database
ISI
SICI code
1523-7060(20010208)3:3<349:IOOSWH>2.0.ZU;2-5
Abstract
[GRAPHICS] Organotelluride 1 is a water-soluble catalyst for the oxidation of iodide w ith hydrogen peroxide in pH 6 phosphate buffer. In two-phase systems, organ ic substrates are efficiently iodinated using 0.8 mol % of catalyst. Water- soluble substrates are iodinated without an organic cosolvent.