Enantioselective rhodium(I)-catalyzed hydrogenation of trifluoromethyl ketones

Authors
Kuroki, Y Sakamaki, Y Iseki, K
Citation
Y. Kuroki et al., Enantioselective rhodium(I)-catalyzed hydrogenation of trifluoromethyl ketones, ORG LETT, 3(3), 2001, pp. 457-459
Citations number
27
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
3
Issue
3
Year of publication
2001
Pages
457 - 459
Database
ISI
SICI code
1523-7060(20010208)3:3<457:ERHOTK>2.0.ZU;2-B
Abstract
[GRAPHICS] The asymmetric hydrogenation of trifluoromethyl ketones to yield chiral alp ha -trifluoromethyl alcohols with enantiomeric excesses up to 98% was achie ved in the presence of chiral rhodium-(amidephosphine-phosphinite) complexe s.