Partially reordering heavily milled intermetallic alloys results in structu
rally and chemically ordered nanometric grains separated by structurally an
d chemically disordered grain boundaries. In systems with disorder induced
ferromagnetism this structural microstructure causes a peculiar magnetic mi
crostructure: paramagnetic grains separated by magnetically ordered (ferrom
agnetic) grain boundaries. This unusual structural-magnetic microstructure
allows for the easy separation of the magnetic contribution of the grain bo
undaries. This contribution is found to be about 15%, suggesting that the g
rain boundary is a few atomic layers thick, in agreement with high-resoluti
on transmission electron microscopy observations.