Synthesis and structure of a novel molybdenum imido calix[6]arene

Authors
Redshaw, C Elsegood, MRJ
Citation
C. Redshaw et Mrj. Elsegood, Synthesis and structure of a novel molybdenum imido calix[6]arene, POLYHEDRON, 19(28), 2000, pp. 2657-2659
Citations number
20
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
POLYHEDRON
ISSN journal
02775387 → ACNP
Volume
19
Issue
28
Year of publication
2000
Pages
2657 - 2659
Database
ISI
SICI code
0277-5387(200012)19:28<2657:SASOAN>2.0.ZU;2-W
Abstract
Treatment of p-tert-butylcalix[6]areneH(6) (H6L) with [Mo(OBu')(2){[2.2'-(N )-C6H4](2)(CH2CH2)}] in refluxing toluene affords, after work-up. the compl ex [Mo(2-NC6H4CH2CH2C6H4NHC(Me)NH-2)LH2]. 4MeCN (1), which contains an 11-m embered metallocyclic ring as characterised by Synchrotron X-radiation. (C) 2000 Elsevier Science B.V. All rights reserved.