An overview is given on the generation of metal nanoparticles dispersed wit
hin amphiphilic polymeric systems, ranging from nonionic polymers and polye
lectrolytes to amphiphilic diblock copolymers. Such materials are receiving
increased attention, since they offer tremendous options for the developme
nt of composites possessing unique catalytic, optical and electronic, or ma
gnetic properties. In this paper emphasis is put on nanosized metal particl
es prepared in situ, that is, in the presence of the polymeric matrix, by w
et-chemistry preparation methods. The choice of the polymer can profoundly
influence the nanoparticle features and the properties of the nanocomposite
s. Copyright (C) 2001 John Wiley & Sons, Ltd.