Aa. Ostroushko et al., Synthesis and physicochemical and catalytic properties of perovskites ABO(3 +/- y) (A = La, Sr, Ag; B=Mn, Co, Fe, Cu, Ti, Mo, V), RUS J AP CH, 73(8), 2000, pp. 1383-1392
The effect is considered exerted by synthesis conditions and composition of
complex oxide materials ABO(3+/-y) based on d metals (Mn, Co, etc.) with p
erovskite structure on their catalytic activity in CO and Il-heptane oxidat
ion. The possibility of using such an empirical parameter as the content of
active oxygen for prognosticating catalytic properties is evaluated. Neutr
on diffraction analysis was applied to determine the structure of the compl
ex oxides and characteristics of particles of these materials.