Sulfide-conducting solid electrolytes

Authors
Kalinina, LA Shirokova, GI Murin, IV Ushakova, YN Fominykh, EG Lyalina, MY
Citation
La. Kalinina et al., Sulfide-conducting solid electrolytes, RUS J AP CH, 73(8), 2000, pp. 1396-1404
Citations number
28
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF APPLIED CHEMISTRY
ISSN journal
10704272 → ACNP
Volume
73
Issue
8
Year of publication
2000
Pages
1396 - 1404
Database
ISI
SICI code
1070-4272(200008)73:8<1396:SSE>2.0.ZU;2-S
Abstract
The possibility is considered that sulfide transport can be achieved, in pr inciple, in phases based on BaZrS3 and MLn(2)S(4) (M = Ca, Ba; Ln = La, Y, Tm, Nd, Sm, Pr). The regions of solid solutions based on ternary compounds were determined. The phases were studied systematically using conductometry , the emf method in chemical concentration cells with and without transfer, and potentiostatic chronoamperometry. A possible mechanism is proposed of defect formation in successive doping of ternary sulfides with binary sulfi des.