The present work summarises the results of a 2-year study of wet-only seque
ntial deposition in 2 rural areas (Alcaniz and Morella) located at differen
t distances from a large coal-fired power station. Precipitation chemistry
Has characterised by relatively high SO42, Ca2+ and NH4+ average concentrat
ions. Sequential study of single precipitation events showed that concentra
tions of most of the ions studied decreased exponentially throughout single
precipitation events. with a sharper decrease in concentrations at the beg
inning of the event. Usually. 40 to 80% of the wet-only deposition of major
ions occurred in the first 2 mm. pll measurements, ranging from 5.6 to 8.1
, showed a decrease in the pH values throughout a precipitation event. Depo
sition levels of Ca2+ I and NH; accounted for the neutralisation of major a
cidic species in the precipitation events except in 5 rain episodes sampled
at Morella. The sequential study of the evolution of the (SO42- + NO3-)/(C
a2+ + NH4+) ratio during a single precipitation allowed us to identify pote
ntial acidic rainfall fractions after an initial volume of precipitation. a
fter most of the Ca2+ in atmospheric particles had been scavenged. A higher
neutralisation capacity was deduced for Alcaniz owing to the higher atmosp
heric levels of natural carbonates and NH4+.