EPR studies of Cu2+ doped zinc saccharin, [Zn(sac)(2)center dot(H2O)(4)]center dot 2H(2)O single crystals

Authors
Kartal, I Karabulut, B Koksal, F Icbudak, H
Citation
I. Kartal et al., EPR studies of Cu2+ doped zinc saccharin, [Zn(sac)(2)center dot(H2O)(4)]center dot 2H(2)O single crystals, Z NATURFO A, 55(11-12), 2000, pp. 887-890
Citations number
17
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES
ISSN journal
09320784 → ACNP
Volume
55
Issue
11-12
Year of publication
2000
Pages
887 - 890
Database
ISI
SICI code
0932-0784(200011/12)55:11-12<887:ESOCDZ>2.0.ZU;2-H
Abstract
The EPR spectra of CU2+ zinc saccharin crystalline powder and single crysta ls have been recorded at room temperature. The angular variation of the spe ctra indicates the substitution of the host Zn2+ with CU2+. Two magneticall y inequivalent sites for Cu2+ have been observed. The spectra were fitted w ith a rhombic spin-Hamiltonian, and the ground state wave function of the c omplex has been constructed.