SELECTIVITY OF THE EPOXIDATION REACTION O F DIMETHYLDIOXIRANE WITH CARBON-CARBON DOUBLE-BONDS IN SOME NATURAL-PRODUCTS

Authors
SUN RQ LIN T HUANG DY WU DJ XUE ZH CHEN JAC
Citation
Rq. Sun et al., SELECTIVITY OF THE EPOXIDATION REACTION O F DIMETHYLDIOXIRANE WITH CARBON-CARBON DOUBLE-BONDS IN SOME NATURAL-PRODUCTS, Gaodeng xuexiao huaxue xuebao, 18(4), 1997, pp. 571-573
Citations number
6
Categorie Soggetti
Chemistry
Journal title
Gaodeng xuexiao huaxue xuebao → ACNP
ISSN journal
02510790
Volume
18
Issue
4
Year of publication
1997
Pages
571 - 573
Database
ISI
SICI code
0251-0790(1997)18:4<571:SOTERO>2.0.ZU;2-H
Abstract
The acetone solution of dimethyldioxirane was prepared with caroate(KH SO5) and acetone. This solution can be kept at low temperature(-20 deg rees C) for days. It is much convenient to use the oxidant for the epo xidation of carbon carbon double bonds in some unsaturated natural pro ducts. Five unsaturated compounds were oxidized to the corresponding e poxides with dimethyldioxirane and the reaction selectivity was discus sed.