A cationic hydroxo-bridged dinuclear gallium complex

Authors
Guzei, IA Dagorne, S Jordan, RF
Citation
Ia. Guzei et al., A cationic hydroxo-bridged dinuclear gallium complex, ACT CRYST C, 57, 2001, pp. 143-144
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
2
Pages
143 - 144
Database
ISI
SICI code
0108-2701(200102)57:<143:ACHDGC>2.0.ZU;2-A
Abstract
The crystal structure of mu -hydroxo-bis{[N-isopropyl-2-(isopropylamino)tro ponimino-N,N'](methyl)gallium(II)} tetrakis(pentafluorophenyl)borate (tropo nimine is 2,4,6-cycloheptatrien-1-imine), [Ga-2(C14H22N2)(2)(OH)]B(C6H5)(4) , is discussed. The two (Pr-i(2)-ATI)GaMe (ATI is aminotroponimime) units o f the dinuclear cation are linked by a bridging hydroxo group and are both slightly twisted from planarity.