Citation
Op. Melnyk et al., (eta(2)-Allylammonium)aquabis(sulfamato-N)copper(I), ACT CRYST C, 57, 2001, pp. 151-153
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701
→ ACNP
Volume
57
Year of publication
2001
Part
2
Pages
151 - 153
Database
ISI
SICI code
0108-2701(200102)57:<151:(>2.0.ZU;2-G
Abstract
The Cu-I atom in the title complex, [Cu(NH2SO3)(2)(C3H8N)(H2O)], is coordin
ated by the C=C bond of the allylammonium cation, two N atoms of the sulfam
ate anions and the O atom of the H2O molecule in the apical position. Thus,
the central atom is in a distorted trigonal-pyramidal environment. Strong
N-H . . .O and O-H . . .O contacts connect separate moieties of the complex
into a three-dimensional framework. The title compound is representative o
f hitherto unknown copper(I)-sulfamate pi -complexes.