Sipeimine, a steroidal alkaloid from Fritillaria roylei Hooker

Citation
Rw. Jiang et al., Sipeimine, a steroidal alkaloid from Fritillaria roylei Hooker, ACT CRYST C, 57, 2001, pp. 170-171
Citations number
5
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
2
Pages
170 - 171
Database
ISI
SICI code
0108-2701(200102)57:<170:SASAFF>2.0.ZU;2-J
Abstract
In the title compound, 3,20-dihydroxycevan-6-one, C27H43NO3, all the six-me mbered rings have normal chair conformations except ring D, which exists in a twist-chair conformation. The five-membered ring C adopts an envelope co nformation. An O-H . . .O hydrogen bond connects the molecules into spirals , which run along the b-axis direction.