A saccharinate-iron(II) complex with a free saccharin molecule present, [Fe(phen)(3)]sac(2)center dot sacH center dot 6H(2)O

Authors
Deng, RMK Simon, S Dillon, KB Goeta, AE
Citation
Rmk. Deng et al., A saccharinate-iron(II) complex with a free saccharin molecule present, [Fe(phen)(3)]sac(2)center dot sacH center dot 6H(2)O, ACT CRYST C, 57, 2001, pp. 4-6
Citations number
12
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
1
Pages
4 - 6
Database
ISI
SICI code
0108-2701(200101)57:<4:ASCWAF>2.0.ZU;2-V
Abstract
The crystal structure of the title compound, tris(1,10-phenanthroline-N,N') iron(II) bis[1,2-benzisothiazol-3(2H)onate 1,1-dioxide] 1,2-benzisothiazol- 3(2H)-one 1,1-dioxide hexahydrate, [Fe(C12H8N2)(3)](C7H4NO3S)(2).C7H5NO3S . 6H(2)O, at 120 K consists of slightly distorted octahedral [Fe(phen)(3)](2 +) cations (phen is 1,10-phenanthroline), two saccharinate anions and a fre e saccharin molecule, as well as six waters of crystallization. The compoun d has been confirmed as diamagnetic low-spin iron(II) by magnetic measureme nts. There is extensive hydrogen bonding leading to a three-dimensional net work.