Tris{bis[N-(2-aminoethyl)-1,2-ethane-diamine-kappa N-3]nickel(II)} bis(tetrathioantimonate)

Authors
Stahler, R Nather, C Bensch, W
Citation
R. Stahler et al., Tris{bis[N-(2-aminoethyl)-1,2-ethane-diamine-kappa N-3]nickel(II)} bis(tetrathioantimonate), ACT CRYST C, 57, 2001, pp. 26-27
Citations number
7
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
1
Pages
26 - 27
Database
ISI
SICI code
0108-2701(200101)57:<26:TNB>2.0.ZU;2-G
Abstract
Yellow crystals of [Ni(deta)(2)](3) [SbS4](2) (deta is diethylenetriamine, C4H13N3) were synthesized under solvothermal conditions by reacting element al Ni, Sb and S in a solution of diethylenetriamine. The structure is compo sed of tetrahedral [SbS4](3-) anions in general positions and octahedral [N i(deta)(2)](2+) cations located at centres of inversion. In the crystal str ucture, the anions and cations are stacked in the direction of the a axis i n a pseudo-hexagonal arrangement.