Bis(O,O '-diisopropyl dithiophosphato-S,S ')(1,10-phenanthroline-N,N ')metal(II)complexes with cadmium(II) and iron(II)

Authors
Hao, QL Yang, XJ Jian, FF Lu, LD Wang, X Razak, IA Chantrapromma, S Fun, HK
Citation
Ql. Hao et al., Bis(O,O '-diisopropyl dithiophosphato-S,S ')(1,10-phenanthroline-N,N ')metal(II)complexes with cadmium(II) and iron(II), ACT CRYST C, 57, 2001, pp. 42-44
Citations number
20
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
1
Pages
42 - 44
Database
ISI
SICI code
0108-2701(200101)57:<42:B'D''>2.0.ZU;2-N
Abstract
The two title compounds, [M(C6H14O2PS2)(2)(C12H8N2)], where M = Cd-II and F e-II, are isomorphous. Each compound has a crystallographic twofold axis of symmetry through the metal atom and the 1,10-phenanthroline molecule. The central metal atom is coordinated to four S atoms from the two dithiophosph ate groups and two N atoms from the 1,10-phenanthroline ligand. The environ ment of the metal atom is a distorted octahedron.