Two iridanonaborane compounds

Citation
J. Bould et al., Two iridanonaborane compounds, ACT CRYST C, 57, 2001, pp. 49-51
Citations number
17
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
1
Pages
49 - 51
Database
ISI
SICI code
0108-2701(200101)57:<49:TIC>2.0.ZU;2-7
Abstract
Two iridanonaborane compounds, 4-carbonyl-5,6:8,9-bis-muH-4-hydrido-4-bis(t rimethylphosphine)-4-irida-arachno-nona- borane(12), [IrH(B8H12)(C3H9P)(2)( CO)], (Ia), and 2-carbonyl-2,5:6,9:8,9-tri-muH-4-chloro-2-bis(trimethylphos phine)-2-irida- nido-nonaborane(11), [Ir(B8H10Cl)(C3H9P)(2)(CO)], (II), are described. Compound (II) shows evidence of effective chlorine-substituent migration during its formation.