A three-dimensional hydrogen-bonded framework in 4,4 '-trimethylenedipiperidinium-2,5-dicarboxybenzene-1,4-dicarboxylate-water (1/1/1)

Authors
Burchell, CJ Ferguson, G Lough, AJ Glidewell, C
Citation
Cj. Burchell et al., A three-dimensional hydrogen-bonded framework in 4,4 '-trimethylenedipiperidinium-2,5-dicarboxybenzene-1,4-dicarboxylate-water (1/1/1), ACT CRYST C, 57, 2001, pp. 92-94
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
1
Pages
92 - 94
Database
ISI
SICI code
0108-2701(200101)57:<92:ATHFI4>2.0.ZU;2-X
Abstract
The title compound is a salt, C13H28N22+.C10H4O82-.H2O. In the anion, there are two short intramolecular hydrogen bonds [O . . .O 2.395 (2) and 2.383 (2) Angstrom; O . . .H . . .O 175 and 172 degrees]. Pairs of anions and pai rs of water molecules are linked by further O-H . . .O hydrogen bonds [O . . .O 2.756 (2) and 2.980 (2) Angstrom; O-H . . .O 171 and 175 degrees] into cyclic centrosymmetric R-6(6)(16) aggregates; these aggregates are linked via the cations into a three-dimensional framework by means of four distinc t N-H . . .O hydrogen bonds [N . . .O 2.787 (2)- 3.204 (2) Angstrom; N-H . . .O 148-173 degrees].