3,3-Diphenyl-6-(p-toluenesulfonyl)-6-aza-3-silabicyclo[3.1.0]hexane

Authors
Matthews, JL Mcarthur, DR Muir, KW White, DNJ
Citation
Jl. Matthews et al., 3,3-Diphenyl-6-(p-toluenesulfonyl)-6-aza-3-silabicyclo[3.1.0]hexane, ACT CRYST C, 57, 2001, pp. 120-122
Citations number
18
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
1
Pages
120 - 122
Database
ISI
SICI code
0108-2701(200101)57:<120:3>2.0.ZU;2-D
Abstract
The title compound, C23H23NO2SSi, at 100 K adopts a boat conformation which brings the CDH bond of an axial phenyl substituent into proximity [C . . . N = 3.376 (1) Angstrom] with the aziridine lone pair. The factors which fav our this conformation for bicyclo[3.1.0]hexane systems are considered.