Development of a jet-REMPI (resonantly enhanced multiphoton ionization) continuous monitor for environmental applications

Citation
H. Oser et al., Development of a jet-REMPI (resonantly enhanced multiphoton ionization) continuous monitor for environmental applications, APPL OPTICS, 40(6), 2001, pp. 859-865
Citations number
9
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science","Optics & Acoustics
Journal title
APPLIED OPTICS
ISSN journal
00036935 → ACNP
Volume
40
Issue
6
Year of publication
2001
Pages
859 - 865
Database
ISI
SICI code
0003-6935(20010220)40:6<859:DOAJ(E>2.0.ZU;2-I
Abstract
The need for a continuous monitor for environmentally important pollutants at realistic [parts-pertrillion (parts in 10(12))] concentrations measured in real time (minutes) is widely recognized. We developed an instrument tha t is based on supersonic-jet expansion and cooling, followed by resonantly enhanced multiphoton ionization (REMPI) into a mass spectrometer. This appr oach furnishes the dual selectivity of narrow-band tuned laser absorption a nd mass analysis. We initiated a spectroscopic characterization of the jet' s collisional cooling behavior to optimize the instrument's sensitivity and selectivity, made measurements of several aromatic compounds (including po lychlorinated dioxins) by use of a one-color REMPI scheme, and demonstrated a two-color excitation scheme. (C) 2001 Optical Society of America OCIS co des: 010.1120, 120.1740.