H. Oser et al., Development of a jet-REMPI (resonantly enhanced multiphoton ionization) continuous monitor for environmental applications, APPL OPTICS, 40(6), 2001, pp. 859-865
The need for a continuous monitor for environmentally important pollutants
at realistic [parts-pertrillion (parts in 10(12))] concentrations measured
in real time (minutes) is widely recognized. We developed an instrument tha
t is based on supersonic-jet expansion and cooling, followed by resonantly
enhanced multiphoton ionization (REMPI) into a mass spectrometer. This appr
oach furnishes the dual selectivity of narrow-band tuned laser absorption a
nd mass analysis. We initiated a spectroscopic characterization of the jet'
s collisional cooling behavior to optimize the instrument's sensitivity and
selectivity, made measurements of several aromatic compounds (including po
lychlorinated dioxins) by use of a one-color REMPI scheme, and demonstrated
a two-color excitation scheme. (C) 2001 Optical Society of America OCIS co
des: 010.1120, 120.1740.