This paper reports high-resolution, moderate to high signal-to-noise ratio
observations of 23 certain Pleiades members, four possible members, and nin
e nonmembers in the Na I D lines, as well as observations of 12 of the star
s in the Na I ultraviolet doublet. In spite of the relative proximity of th
e stars to the sun (even most of the nonmembers lie within 200 pc), the lin
e profiles exhibit remarkable complexity, with up to five absorption compon
ents and equally remarkable star-to-star variation. The velocity range, 2-2
0 km s(-1), conforms well to the range expected for gas deflected by the pa
ssage of the cluster. The paper includes a careful discussion of uncertaint
ies in the data, the most important conclusions of which are that the veloc
ity scatter is consistent with that expected from random errors in the wave
length calibration and that systematic errors probably are less than or sim
ilar to0.1 km s(-1). Appendices detail the choice of stellar data and the p
rocedure adopted for removing telluric absorption lines. Analysis follows i
n a separate paper.