Increased selectivity in hydroformylation reactions using dendrimer based catalysts; a positive dendrimer effect

Authors
Ropartz, L Morris, RE Foster, DF Cole-Hamilton, DJ
Citation
L. Ropartz et al., Increased selectivity in hydroformylation reactions using dendrimer based catalysts; a positive dendrimer effect, CHEM COMMUN, (4), 2001, pp. 361-362
Citations number
12
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
4
Year of publication
2001
Pages
361 - 362
Database
ISI
SICI code
1359-7345(2001):4<361:ISIHRU>2.0.ZU;2-X
Abstract
Dendrimers based on polyhedral oligomeric silsesquioxanes (POSS) cores with 16 PPh2 arms give much higher linear selectivities (14:1) than their small molecule analogues (3-4:1) in the hydroformylation of oct-1-ene.