Hydrolysis of phosphodiester with hydroxo- or carboxylate-bridged dinuclear Ni(II) and Cu(II) complexes

Authors
Yamaguchi, K Akagi, F Fujinami, S Suzuki, M Shionoya, M Suzuki, S
Citation
K. Yamaguchi et al., Hydrolysis of phosphodiester with hydroxo- or carboxylate-bridged dinuclear Ni(II) and Cu(II) complexes, CHEM COMMUN, (4), 2001, pp. 375-376
Citations number
13
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
4
Year of publication
2001
Pages
375 - 376
Database
ISI
SICI code
1359-7345(2001):4<375:HOPWHO>2.0.ZU;2-F
Abstract
A hydroxo- or carboxylate-bridged dinuclear Ni(II) complexes with N,N,N',N' -tetrakis{(6-methyl-2-pyridyl)methyl}-1,3-diaminopropan-2-ol has been synth esized as models for Ni(II)-substituted phosphotriesterase, which are more active catalysts for hydrolysis of phosphodiester than the corresponding di nuclear Cu(II) and Zn(II) complexes.