[(BuNHP)-N-t(mu-NBut)(2)PNH2], a novel building block for neutral and anionic polycyclic main group arrangements

Authors
Beswick, MA Elvidge, BR Feeder, N Kidd, SJ Wright, DS
Citation
Ma. Beswick et al., [(BuNHP)-N-t(mu-NBut)(2)PNH2], a novel building block for neutral and anionic polycyclic main group arrangements, CHEM COMMUN, (4), 2001, pp. 379-380
Citations number
24
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
4
Year of publication
2001
Pages
379 - 380
Database
ISI
SICI code
1359-7345(2001):4<379:[ANBBF>2.0.ZU;2-K
Abstract
The novel precursor [(BuNHP)-N-t(mu -NBut)(2)PNH2] (1) provides easy access to polycyclic main group systems; reaction with Sb(NMe2)(3) gives the tric yclic species {[(BuNHP)-N-t(mu -NBut)(2)- P}(2){Me2NSb(mu -N)}(2)] (2), whe reas reaction with an excess of (BuLi)-Li-n results in elimination of LiNH2 and the formation of the co-complex [{(BuNP)-N-t(mu -NBut)(2)P}(2)N]Li-3 ( (BuLi)-Li-n)(2), (3), containing the unprecedented [{(BuNP)-N-t(mu -NBut)(2 )P}(2)N](3-) trianion.