X. Liu et al., Plasma-assisted MOCVD growth of superconducting NbN thin films using Nb dialkylamide and Nb alkylimide precursors, CHEM VAPOR, 7(1), 2001, pp. 25
The first example of the use of metal-organic precursors for depositing NbN
superconducting thin films is described. The study, which employed niobium
(IV) and niobium(v) (see Figure) pulsed source precursors and hydrazine pla
sma as the nitrogen source, indicates that T-c is highly dependent on the l
attice parameters and level of oxygen impurities, which are in turn governe
d by growth and post-deposition annealing temperatures.