Synthesis and spectroscopic and electrochemical characterisation of a conducting polythiophene bearing a chiral beta-substituent: Polymerisation of (+)-4,4 '-bis[(S)-2-methylbutylsulfanyl]-2,2 '-bithiophene
D. Iarossi et al., Synthesis and spectroscopic and electrochemical characterisation of a conducting polythiophene bearing a chiral beta-substituent: Polymerisation of (+)-4,4 '-bis[(S)-2-methylbutylsulfanyl]-2,2 '-bithiophene, CHEM-EUR J, 7(3), 2001, pp. 676-685
A regioregular head-to-head/tail-to-tail poly(beta,beta'-disubstituted bith
iophene) P1 was synthesised by chemical and electrochemical polymerisation
of 2,2'-bithiophene that bears (S)-2-methylbutylsulfanyl chains in the beta
and beta'-positions. The polymer was characterised by GPC, NMR and UV/Vis
spectroscopy, CD, AFM and by electrochemical and conductivity measurements.
The CD spectra of P1 in solutions in which poor solvents are present show
interesting features and allow the presence of different optically active s
pecies to be distinguished. Upon varying the casting conditions of P1, diff
erent relative amounts of grainy and homogeneous aggregated phases were obs
erved in AFM micrographies of films and corresponding negative or positive
first Cotton effects were found in the CD spectra. AFM, CD and UV/Vis chara
cterisations were also performed on an electrogenerated optically active po
lymer PE1. in order to make a comparison with the chemically synthesised on
e. The interesting, small band gap of P1 allows for easy p- and n-electroch
emical doping.