Air bubbles and clathrate hydrates in the transition zone of the NGRIP deep ice core

Field studies of air bubble and clathrate Inclusions in the NGRIP ice core reveal two stages of clathrate formation. In the transition zone translucen t primary clathrates with rough surfaces and irregular shapes, formed from individual bubbles, split up and form smaller specimens. Deeper down in the transition zone (similar to 1100 m), clathrate metamorphosis sets in, givi ng rise to the formation of transparent secondary clathrates, with smooth a nd regular, often polyhedral or faceted shapes. Rod-like crystals of great length (similar to 2 mm) often show signs of separation into smaller units that fragment into smaller specimens. These findings imply that the simplif ied picture of one bubble forming one clathrate has to be modified.