The knowledge of the characteristics of unused, excess and untapped exergy
allows a thorough analysis of internal energy hows distribution within a so
rption heat pump. It can be applied to any system based on gas-liquid absor
ption, adsorption or solid-gas reaction as well as to any process based on
the internal recycling of the energy flux. It can also be applied for the c
ase of a simple effect ideal machine, in particular in the definition of pr
ocesses where the COP is larger than 2: the levels at which the initial exe
rgy is downgraded on the one hand, as well as, the upgraded excess exergy p
roduced on the other allows the designer to make a judicious choice of a sy
stem. (C) 2001 Elsevier Science Ltd and IIR. All rights reserved.