Exchange energy in a double-well potential profile from fluctuation theory

This article shows that the asymptotic quantum mechanical exchange energies and wave functions in a bistable potential can be obtained by computing th e complex-valued first-passage time across the potential barrier from a tra nsient state endowed with Smoluchowski boundary conditions, whose probabili ty density is concentrated on one side of the barrier. This interpretation is validated by one of the authors' previous work on diffusion in a random field, showing that this model yields a diffusion equation equivalent to qu antum mechanical equations. (C) 2001 American Institute of Physics.