J. Togawa et al., Freeze-purged-desorption method for quantitative evaluation of CO2-solubility in polymeric films, J MEMBR SCI, 182(1-2), 2001, pp. 125-128
A new experimental method, named as freeze-purged-desorption (FPD) method,
to evaluate quantitatively the amount of gases sorbed in polymeric films, h
as been developed by using carbon dioxide gas and five different films (low
density polyethylene: LDPE, polypropylene: PP, polystyrene: PS, polyacrylo
nitrile copolymer: PAN, polycarbonate: PC). The FPD method consisted of thr
ee operational periods of time based on the stepwise change in the system t
emperatures, the freeze periods of sorbed CO2 at -196 degreesC, the purging
period of atmospheric CO2 at -78 degreesC and the desorption period of the
freezed CO2 in the film at -9 degreesC. The evaluated values for LDPE, PP,
PS, PAN and PC were 0.310, 0.65, 3.90, 0.098 and 6.90 (cm(3)(STP)/cm(3) at
m), respectively, which were about 20-40% higher than the reference values.
The validity of the method was reconfirmed by a good reproducibility of th
e desorption curves of sorbed gases referring to a blank curve obtained fro
m the non-porous glass beads. (C) 2001 Elsevier Science B.V. All rights res
erved.