Influence of membrane morphology on the flux decline during dead-end ultrafiltration of refinery and petrochemical waste water

Reuse of refinery and petrochemical effluent, high in turbidity and salinit y, as cooling water was proposed by a treatment scheme comprising ultrafilt ration (UF) and reverse osmosis (RO). Dead-end UF was investigated in this study to reduce the turbidity of the waste water prior to RO, which was nec essary to decrease the salinity to an acceptable level for reuse as cooling water and/or boiler feed water. UF tests were performed at constant transm embrane pressure (0.2 bar) using hollow fiber polyethersulphone membranes c oated with polyvinylpirrolidone. UF membranes with two different molecular weight cut-offs (50 and 150 kDa) were compared. The two membranes performed very differently, i.e. the 150 kDa membrane showed a very fast flux declin e (i.e. 20% in 2 min) requiring frequent backwashing (BW), whereas in the c ave of the 50 kDa membrane. 20% flux decline was reached in 20 min. An anal ysis of the blocking mechanisms could not explain the rapid drop in flux fo r the 150 kDa membrane as compared with the 50 kDa membrane, since a gradua l change from complete to intermediate blocking and cake filtration was obs erved in both cases. However, a held emission scanning electron microscopy (FESEM) analysis of both UF membranes suggested that the superior filtratio n performance may be due to the highly interconnected pore system of the 50 kDa membrane, resulting in a '3D-bridge-type' surface morphology. (C) 2001 Elsevier Science B.V. All rights reserved.