Bound ro-vibronic states of triplet H-3+

Citation
O. Friedrich et al., Bound ro-vibronic states of triplet H-3+, PHYS REV L, 86(7), 2001, pp. 1183-1186
Citations number
18
Categorie Soggetti
Physics
Journal title
PHYSICAL REVIEW LETTERS
ISSN journal
00319007 → ACNP
Volume
86
Issue
7
Year of publication
2001
Pages
1183 - 1186
Database
ISI
SICI code
0031-9007(20010212)86:7<1183:BRSOTH>2.0.ZU;2-T
Abstract
On the basis of a new, highly accurate potential energy hypersurface for th e lowest triplet state of H-3(,)+ (3)Sigma (+)(u), the bound ro-vibronic st ates are calculated for J less than or equal to 5. Since the potential has very shallow minima, those states exist only up to single vibrational excit ation. The symmetry properties of the re-vibrational states are investigate d. Further, it is demonstrated that the first excited triplet state, which intersects conically with the (3)Sigma (+)(u) state, has no effect on the r eported re-vibrational energies.