Self-assembled growth of an ordered layer of Pt-Br-Pt chains on a Ft(110) s
urface is demonstrated. Upon slight doping with excess bromine, charge-dens
ity wave (CDW) domains separated by well-localized solitons are observed in
the Br/Pt layer by scanning tunneling microscopy. Depending on annealing a
nd adatom concentration, a global, long-range-ordered CDW ground state can
be established. Angle-resolved UV photoemission data reveal the correspondi
ng Fermi surface and its removal upon the Peierls transition. The CDW phase
is stable to well above room temperature.