Thermodynamic calculation of the equilibrium composition in the system CH4-NH3-O-2 in the presence of formic acid in reaction products

Authors
Trusov, NV Grin', GI Prezhdo, VV
Citation
Nv. Trusov et al., Thermodynamic calculation of the equilibrium composition in the system CH4-NH3-O-2 in the presence of formic acid in reaction products, RUS J AP CH, 73(9), 2000, pp. 1517-1521
Citations number
17
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF APPLIED CHEMISTRY
ISSN journal
10704272 → ACNP
Volume
73
Issue
9
Year of publication
2000
Pages
1517 - 1521
Database
ISI
SICI code
1070-4272(200009)73:9<1517:TCOTEC>2.0.ZU;2-A
Abstract
The use of the modified Hooke-Jeaves method made it possible to calculate t he equilibrium composition formed in oxidative ammonolysis of methane (Andr ussow method). The thermodynamic conditions are studied under which HCOOH i s formed in the course of ammonolysis and is subsequently converted into hy drogen cyanide.