Ta. Kochina et al., Ion-molecule reactions of monosubstituted ethylsilylium ions with trimethyl(tert-butylamino)silane in the gas phase, RUSS J G CH, 70(8), 2000, pp. 1233-1236
Reaction of nuclear-chemically generated ethylsilylium ions with trimethyl(
tert-butylamino)silane in the gas phase was studied. In the course of react
ion the ethylsilylium ion completely isomerizes into the dimethylsilylium i
on. Experiments show that the pathway involving proton transfer practically
is not realized, in contrast to the reactions of carbenium ions with amine
s.