Ion-molecule reactions of monosubstituted ethylsilylium ions with trimethyl(tert-butylamino)silane in the gas phase

Authors
Kochina, TA Shchukin, EV Nefedov, VD Sinotova, EN
Citation
Ta. Kochina et al., Ion-molecule reactions of monosubstituted ethylsilylium ions with trimethyl(tert-butylamino)silane in the gas phase, RUSS J G CH, 70(8), 2000, pp. 1233-1236
Citations number
32
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
70
Issue
8
Year of publication
2000
Pages
1233 - 1236
Database
ISI
SICI code
1070-3632(200008)70:8<1233:IROMEI>2.0.ZU;2-N
Abstract
Reaction of nuclear-chemically generated ethylsilylium ions with trimethyl( tert-butylamino)silane in the gas phase was studied. In the course of react ion the ethylsilylium ion completely isomerizes into the dimethylsilylium i on. Experiments show that the pathway involving proton transfer practically is not realized, in contrast to the reactions of carbenium ions with amine s.