Thermal reactions of phenylacetylene with a mixture of thiophenol and dialkyl diselenide

Authors
Shilkina, TA Papernaya, LK Deryagina, EN Albanov, AI
Citation
Ta. Shilkina et al., Thermal reactions of phenylacetylene with a mixture of thiophenol and dialkyl diselenide, RUSS J G CH, 70(8), 2000, pp. 1256-1258
Citations number
6
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
70
Issue
8
Year of publication
2000
Pages
1256 - 1258
Database
ISI
SICI code
1070-3632(200008)70:8<1256:TROPWA>2.0.ZU;2-0
Abstract
Heating to phenylacetylene with a mixture of thiophenol and dialkyl diselen ide to 150-180 degreesC yields previously unknown products of simultaneous addition to the phenylacetylene triple bond of alkyl-selenyl and phenthiyl groups, 2-alkylselenyl-1-phenyl-1-phenylthioethenes. The free-radical react ion mechanism is discussed.