Complexation of N-alkyltetraphenylporphyrin with d-metal 8-quinolinolates

Authors
Mamardashvili, GM Berezin, BD
Citation
Gm. Mamardashvili et Bd. Berezin, Complexation of N-alkyltetraphenylporphyrin with d-metal 8-quinolinolates, RUSS J G CH, 70(8), 2000, pp. 1299-1303
Citations number
11
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
70
Issue
8
Year of publication
2000
Pages
1299 - 1303
Database
ISI
SICI code
1070-3632(200008)70:8<1299:CONWD8>2.0.ZU;2-G
Abstract
The kinetics of coordination of N-methyl-substituted tetraphenylporphyrin [ (H, CH3)P] to Cu(II), Zn(II), Mn(II), Ni(II), Co(II), Cd(II), Ag(I), and Hg (II) 8-quinolinolates [M(L-1)(2)] in DMSO was studied. The reaction yields metalloporphyrins (L-1)M(CH3)P and MP or intermediates M(L-2)(2). (H,CH3)P depending of the reaction conditions and the metal nature. The rate of form ation of (L-1)M(CH3)P is maximal for group II d-metal quinolinolates.