Synthesis of paddlanes having a bicyclo[1.1.1]pentane core. The consequences of olefin metathesis involving unsaturated 1,3-dicarboxylate esters of varying chain length

Authors
Paquette, LA Mendez-Andino, J
Citation
La. Paquette et J. Mendez-andino, Synthesis of paddlanes having a bicyclo[1.1.1]pentane core. The consequences of olefin metathesis involving unsaturated 1,3-dicarboxylate esters of varying chain length, TETRAHEDR L, 42(6), 2001, pp. 967-970
Citations number
30
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
6
Year of publication
2001
Pages
967 - 970
Database
ISI
SICI code
0040-4039(20010205)42:6<967:SOPHAB>2.0.ZU;2-S
Abstract
Described herein is the synthesis of an homologous series of bicyclo[1.1.1] pentane-1,3-dicarboxylate esters featuring omega -alkenols of differing cha in length (n=4-8) For the purpose of evaluating their ability to undergo ri ng-closing metathesis/paddlane formation in the presence of Grubbs' catalys t. (C) 2001 Elsevier Science Ltd. All rights reserved.