Synthesis of (+/-)-demethoxypauciflorine B and (+/-)-pauciflorine B from (+/-)-11,12-demethoxylahadinine B and (+/-)-lahadinine B, respectively via aperoxycarbanolamine fragmentation reaction

Authors
Magnus, P Hobson, LA Westlund, N Lynch, V
Citation
P. Magnus et al., Synthesis of (+/-)-demethoxypauciflorine B and (+/-)-pauciflorine B from (+/-)-11,12-demethoxylahadinine B and (+/-)-lahadinine B, respectively via aperoxycarbanolamine fragmentation reaction, TETRAHEDR L, 42(6), 2001, pp. 993-997
Citations number
13
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
6
Year of publication
2001
Pages
993 - 997
Database
ISI
SICI code
0040-4039(20010205)42:6<993:SO(BA(>2.0.ZU;2-T
Abstract
Conversion of 11,12-demethoxylahadinine B 3 and lahadinine B 2 into 11,12-d emethoxypauciflorine B 6 and pauciflorine B 5, respectively, was achieved b y treatment with AgBF4/THF followed by EtOAc/MeCO3H. (C) 2001 Elsevier Scie nce Ltd. All rights reserved.