Labile P-C bonds: P-(phosphinoyl)methyl-lambda(5)-phosphazenes and relatedcompounds

Authors
Alajarin, M Lopez-Leonardo, C Llamas-Lorente, P
Citation
M. Alajarin et al., Labile P-C bonds: P-(phosphinoyl)methyl-lambda(5)-phosphazenes and relatedcompounds, TETRAHEDR L, 42(6), 2001, pp. 1041-1043
Citations number
15
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
6
Year of publication
2001
Pages
1041 - 1043
Database
ISI
SICI code
0040-4039(20010205)42:6<1041:LPBPAR>2.0.ZU;2-J
Abstract
N-Aryl-P,P-diphenyl-P-(diphenylphosphinoyl)mrthyl-lambda (5)-phosphazenes u ndergo smooth acid-catalysed hydrolysis with concomitant PC bond fission yi elding N-aryl-P,P-diphenylyhosphinamides and diphenylmethylphosphane oxide. A tentative mechanistic explanation is given. (C) 2001 Elsevier Science Lt d. All rights reserved.