A 3-D computational fluid-dynamics model containing equations for mass, hea
t and momentum transfer and using a k-epsilon closure model, was used to ca
lculate the 3-D flue-gas flow pattern and the corresponding 3-D temperature
field for a pyrolysis furnace. The computational fluid dynamics model is c
ombined with a reactor model for the cracking tubes and a radiation model f
or the radiative heat transfer in the furnace box. Detailed reaction kineti
cs for the naphtha cracking reactions in the tubes and a five-step reaction
mechanism for the combustion of methane in the flames were used. This comp
lete model reveals asymmetric flow patterns in a naphtha-cracking furnace w
ith 4/2/1 split-coil reactors and fired with long-flame burners.