The growth mode and electronic structures of Fe thin films, epitaxially gro
wn on Rh(001), were studied by various photoemission measurements for the f
ilm thickness of 0-12 monolayers. By comparing the valence band structures
obtained from the angle-resolved photoemission spectra and the theoretical
band calculations for the bulk Fe, we concluded that the valence band struc
ture of the Fe film resembles that of fcc(001) in the low coverage region a
nd that of bcc(110) in the high coverage region. This transformation of the
electronic structure is considered to be related to the thickness dependen
ce of the interlayer spacing of the films. (C) 2001 Elsevier Science B.V. A
ll rights reserved.